Mary-Kate Olsen spent her second day on the set Tuesday of ABC’s comedy Samantha Who for a one-episode appearance this fall, the network confirms.

Olsen, 22, plays a self-destructive bad girl who reminds Samantha (Christina Applegate) of her younger self, but on the set she was all business, Executive Producer Don Todd tells PEOPLE.

“She showed up alone, ready to work, is great on set and is serious about the job,” says Todd. “This is a girl who’s been in front of the camera almost literally her entire life. She’s smart, and she knows what she’s doing.”

Olsen has been stepping out in comedies as of late – she starred as Tara Lindman on Showtime’s Weeds last year – and can be seen opposite Ben Kingsley in the film The Wackness, which hits theaters on July 3. –Pamela Warrick

Rich, semi-famous people like Mary-Kate Olsen, Nicole Richie and Joel Madden have a lot of time on their hands. When they’re not laughing at the homeless, they’re throwing whacked out parties like this. These parties usually have themes that are a throwback to a phase they grew out of from their childhood. For example, gangster rap/the urban lifestyle, flannel and minorities. Here is one of those parties. The theme was flannel, but the outcome was all retardation.

[Images via ONTD]